A pnictogen of peculiar posture.

Cationic phosphorus-carbon-pnictogen cages isolobal to [C5R5]+.

The cationic cages nido-[C2Bu(t)2P2E]+ (E = As, Sb), which are isolobal to the cyclopentadienyl cation, adopt square based pyramidal structures with the heavy pnictogen atom at the apex; NMR and computational methods have been used to probe the dynamic behaviour of the complexes.

Pnictogen-directed synthesis of discrete disulfide macrocycles.

Cyclic disulfide macrocycles were rapidly synthesized cleanly and selectively from rigid dithiols via oxidation with iodine when activated by pnictogen additives (As and Sb). Macrocycles were confirmed by (1)H-NMR spectroscopy and X-ray crystallography. A p-xylyl-based disulfide trimer and tetramer crystallized in hollow, stacked columns stabilized by intermolecular, sulfur···sulfur close conta...

Chemistry of the Terminal Pnictogen Complexes of Lead, Tin and Germanium

A Peculiar Case of Splenic Marginal Zone Lymphoma and Review of Literature

Synthesis of III-V Nanocrystals by Co-reduction Reactions

This paper describes a co-reduction colloidal method for the synthesis of In-containing III-V nanocrystals (NCs) by using pnictogen halides (such as PCl3, AsCl3, and SbCl3) as the pnictogen-sources and superhydride (LiBH(C2H5)3) as the reducing agent. The syntheses were generally carried out in octadecene in the presence of fatty acids at ~250 oC. The as-synthesized InP NCs were quasi-monodispe...